It looks quite good, the character is perfectly cut out (usually people don't do a great job with that).
I only have 2 things that I would change a bit:
- The background seems too busy, although since you don't have many things is not a big problem
- The curvy black line is a little blurry and seems to be cutoff on the left end, and missing a bit on the top curve, it looks too flat on that section...
Great start nonetheless. My first attempts with PSP or PS where just awful.
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